From: John Fields on
On Sat, 26 Jun 2010 08:39:29 -0700 (PDT), Bill Sloman
<bill.sloman(a)ieee.org> wrote:

>On Jun 26, 3:43�pm, Raveninghorde <raveninghorde(a)invalid> wrote:
>> On Sat, 26 Jun 2010 06:13:42 -0500, John Fields
>>
>>
>>
>> <jfie...(a)austininstruments.com> wrote:
>> >On Fri, 25 Jun 2010 16:48:54 -0700 (PDT), Bill Sloman
>> ><bill.slo...(a)ieee.org> wrote:
>>
>> >>On Jun 26, 1:11 am, Raveninghorde <raveninghorde(a)invalid> wrote:
>> >>> I am used to charging NiCd or NiMH cells however I haven't done it
>> >>> from a solar panel before. I'm happy I can hold the solar panel near
>> >>> the point of peak efficiency but I am concerned about charge
>> >>> termination due to the variable power available from solar panels.
>>
>> >>> Normally for NiCd I would use negative delta V for termination with a
>> >>> back up timer. For NiMH I would use a thermistor for delta T
>> >>> termination. However I can see potential problems with solar as the
>> >>> power source.
>>
>> >>> In principle I could lay out a 60W panel in Arizona and charge the
>> >>> batteries without problems - until someone parks a truck and shades
>> >>> the panel dropping the charge current.
>>
>> >>> So what is the best way to terminate charge on nickel based batteries
>> >>> with a variable power source?
>>
>> >>http://www.edn.com/file/25378-Solar_panel_powers_two_stage_lead_acid_...
>>
>> >---
>> >OP: ... "nickel based batteries"...
>>
>> >BS: ... "lead acid battery charger"...
>>
>> >http://csmanagement.files.wordpress.com/2009/08/apple-and-orange.jpg
>>
>> Yep, diiferent. Lead acid and lithium are fairly easy to terminate the
>> charge on as they use constant voltage charging.
>
>Nickel-based batteries are fairly easy to keep track off if you can
>put a temperature sensor on the battery, and a reference temperature
>sensor fairly close by.
>
>Once nickel cadmium bateries are fully charged, any further changing
>liberates hydrogen gas at the cathode, which diffuses to the anode and
>recombines with oxygen (from the metal oxide produced by the same
>current) to produce water and heat - quite a lot more heat than is
>generated by the same current when it is charging a less than fully
>charged battery.
>
>"Interchangable" thermistors are quite stable enough to let you
>reliably detect the consequent extra heating of the battery.
>
>http://en.wikipedia.org/wiki/Nickel-metal_hydride_battery

---
So it looks like, without expressly acknowledging your earlier
boo-boo, you've admitted that your reference was bogus since a PV
lead-acid charger won't work for NiMH.

Unfortunately, and to your detriment, you still haven't addressed the
OP's query, which was, basically, "What do I do if the sun goes behind
a cloud while the battery is charging?"

Instead, you parrot an expensive "Interchangeable thermistor" scheme
to guard against overcharging, which the OP has already laid out, but
which has nothing to do with PV shading during charging.

The way I'd do it would be to completely disconnect the battery from
the charging circuitry when the array was shadowed, and then reconnect
it when the sun came out again.

Got a better idea?

From: Kevin McMurtrie on
In article <101c265ga7vldq4bmcs5mkuv8c1qsutd4c(a)4ax.com>,
Raveninghorde <raveninghorde(a)invalid> wrote:

> On Fri, 25 Jun 2010 22:03:37 -0700, Kevin McMurtrie
> <mcmurtrie(a)pixelmemory.us> wrote:
>
> >In article <16da261ntm8hp49umugnu0lvmq54rlmgrv(a)4ax.com>,
> > Raveninghorde <raveninghorde(a)invalid> wrote:
> >
> >> I am used to charging NiCd or NiMH cells however I haven't done it
> >> from a solar panel before. I'm happy I can hold the solar panel near
> >> the point of peak efficiency but I am concerned about charge
> >> termination due to the variable power available from solar panels.
> >>
> >> Normally for NiCd I would use negative delta V for termination with a
> >> back up timer. For NiMH I would use a thermistor for delta T
> >> termination. However I can see potential problems with solar as the
> >> power source.
> >>
> >> In principle I could lay out a 60W panel in Arizona and charge the
> >> batteries without problems - until someone parks a truck and shades
> >> the panel dropping the charge current.
> >>
> >> So what is the best way to terminate charge on nickel based batteries
> >> with a variable power source?
> >
> >Keep a device on the battery that measures all current in and out. It
> >can estimate the charge power well enough to prevent wear.
> >
> >LiFePO4 and Li-Po are other options. They'll give you the same power
> >rate, much better density, less self-discharge in AZ heat, and simpler
> >charging.
>
> I don't get to measure current out of the battery, the state of charge
> will be unknown when the battery is put on the charger.
>
> Unfortunately the customer specifies Nickel based batteries.

Not many options left. I've never seen a process to determine NiMH
charge level without the use of a long and continuous high current. If
you look at all the graphs from manufacturers, you'll see that there are
no absolute values to use as triggers. They're all deltas and they're
only valid for a range of currents.

- Put a LiFePO4 in the solar charger and transfer that to the NiMH.

- Let the battery hit thermal cut-off and derate the life expectancy.

- Use proprietary fast-charge NiHM cells that have a gas pressure sensor.
--
I won't see Google Groups replies because I must filter them as spam
From: Bill Sloman on
On Jun 27, 1:14 am, John Fields <jfie...(a)austininstruments.com> wrote:
> On Sat, 26 Jun 2010 08:39:29 -0700 (PDT), Bill Sloman
>
> <bill.slo...(a)ieee.org> wrote:
> >On Jun 26, 3:43 pm, Raveninghorde <raveninghorde(a)invalid> wrote:
> >> On Sat, 26 Jun 2010 06:13:42 -0500, John Fields
>
> >> <jfie...(a)austininstruments.com> wrote:
> >> >On Fri, 25 Jun 2010 16:48:54 -0700 (PDT), Bill Sloman
> >> ><bill.slo...(a)ieee.org> wrote:
>
> >> >>On Jun 26, 1:11 am, Raveninghorde <raveninghorde(a)invalid> wrote:
> >> >>> I am used to charging NiCd or NiMH cells however I haven't done it
> >> >>> from a solar panel before. I'm happy I can hold the solar panel near
> >> >>> the point of peak efficiency but I am concerned about charge
> >> >>> termination due to the variable power available from solar panels.
>
> >> >>> Normally for NiCd I would use negative delta V for termination with a
> >> >>> back up timer. For NiMH I would use a thermistor for delta T
> >> >>> termination. However I can see potential problems with solar as the
> >> >>> power source.
>
> >> >>> In principle I could lay out a 60W panel in Arizona and charge the
> >> >>> batteries without problems - until someone parks a truck and shades
> >> >>> the panel dropping the charge current.
>
> >> >>> So what is the best way to terminate charge on nickel based batteries
> >> >>> with a variable power source?
>
> >> >>http://www.edn.com/file/25378-Solar_panel_powers_two_stage_lead_acid_...
>
> >> >---
> >> >OP: ... "nickel based batteries"...
>
> >> >BS: ... "lead acid battery charger"...
>
> >> >http://csmanagement.files.wordpress.com/2009/08/apple-and-orange.jpg
>
> >> Yep, diiferent. Lead acid and lithium are fairly easy to terminate the
> >> charge on as they use constant voltage charging.
>
> >Nickel-based batteries are fairly easy to keep track off if you can
> >put a temperature sensor on the battery, and a reference temperature
> >sensor fairly close by.
>
> >Once nickel cadmium bateries are fully charged, any further changing
> >liberates hydrogen gas at the cathode, which diffuses to the anode and
> >recombines with oxygen (from the metal oxide produced by the same
> >current) to produce water and heat - quite a lot more heat than is
> >generated by the same current when it is charging a less than fully
> >charged battery.
>
> >"Interchangable"  thermistors are quite stable enough to let you
> >reliably detect the consequent extra heating of the battery.
>
> >http://en.wikipedia.org/wiki/Nickel-metal_hydride_battery
>
> ---
> So it looks like, without expressly acknowledging your earlier
> boo-boo, you've admitted that your reference was bogus since a PV
> lead-acid charger won't work for NiMH.
>
> Unfortunately, and to your detriment, you still haven't addressed the
> OP's query, which was, basically, "What do I do if the sun goes behind
> a cloud while the battery is charging?"

That was the content of the EDN article I pointed to.

http://www.edn.com/file/25378-Solar_panel_powers_two_stage_lead_acid_battery_charger_pdf.pdf

Why don't you read it? It didnn't address the specific problem posed
by Ravinghorde's customer's choice of battery, but somebody with a
little more imagination than Ravinghorde might be able to adapt the
ideas presented.

> Instead, you parrot an expensive "Interchangeable thermistor" scheme
> to guard against overcharging, which the OP has already laid out, but
> which has nothing to do with PV shading during charging.

For PV shading during charging, you need something like a ringing
choke inverter, that uses a low voltage source to build up current
through an inductor, then switches "charged" inductor to discharge
into the battery bank at a voltage determined by the battery bank.

Ringing-choke inverters don't exploit core material particularly
efficiently, and there are a variety of more complicated schemes
around. Linear Technology makes a fuss about its ics that can be used
to build buck-boost SEPIC converters.

I've never played with them, so I don't know much about the area.

Ravinghordes delta-T charge termination scheme only uses a single
thermistor to detect the jump in temperature when the cells go over to
hydrogen generation; this is cheaper than using and monitoring two
thermistors, but there are situations where the delta-T can be masked
or faked by the environment.

> The way I'd do it would be to completely disconnect the battery from
> the charging circuitry when the array was shadowed, and then reconnect
> it when the sun came out again.
>
> Got a better idea?

The ringing choke - or one of the elaborations of that basic idea -
can be used to step up the solar cell output voltage more when the
cells are shaded so that the batteries continue to be charged, albeit
more slowly, when there is less sun around.

It's obviously a better idea than yours, but it is scarcely mine -
people have been doing it for years.

--
Bill Sloman, Nijmegen

From: dagmargoodboat on
On Jun 26, 7:37 pm, Kevin McMurtrie <mcmurt...(a)pixelmemory.us> wrote:

> - Use proprietary fast-charge NiHM cells that have a gas pressure sensor.

That's not a bad idea--Ray-O-Vac made some of those. 15-minute
charging, I believe,
so you load them at about 4.5C.

The problem with temperature cut-outs and fast charging is that once
a cell's full, it still takes a while to heat up. So, you wind up
overcharging
a bit every time, which cuts the cell's service life.

A little OT, but the NiMH comments here were interesting--

http://translogic.aolautos.com/2010/06/24/charged-up-about-batteries-why-are-they-so-expensive/

* Limited service life. If repeatedly deep-cycled, (i.e., the
charge is completely depleted and then recharged, especially at high
load currents), battery performance begins to deteriorate after 200 to
300 cycles.

* Limited discharge current. Repeated discharges with high load
currents reduce the battery's cycle life.

* Sensitive to high temperatures. Performance degrades if stored
at elevated temperatures. NiMH batteries should be stored in a cool
place and at a state-of-charge of about 40 percent.

* Maintenance. NiMH batteries require regular full discharge to
prevent crystalline formation.

They say they can make an NiMH pack last the life of a car.

--
Cheers,
James Arthur
From: Raveninghorde on
On Sat, 26 Jun 2010 18:14:46 -0500, John Fields
<jfields(a)austininstruments.com> wrote:

>On Sat, 26 Jun 2010 08:39:29 -0700 (PDT), Bill Sloman
><bill.sloman(a)ieee.org> wrote:
>
>>On Jun 26, 3:43�pm, Raveninghorde <raveninghorde(a)invalid> wrote:
>>> On Sat, 26 Jun 2010 06:13:42 -0500, John Fields
>>>
>>>
>>>
>>> <jfie...(a)austininstruments.com> wrote:
>>> >On Fri, 25 Jun 2010 16:48:54 -0700 (PDT), Bill Sloman
>>> ><bill.slo...(a)ieee.org> wrote:
>>>
>>> >>On Jun 26, 1:11 am, Raveninghorde <raveninghorde(a)invalid> wrote:
>>> >>> I am used to charging NiCd or NiMH cells however I haven't done it
>>> >>> from a solar panel before. I'm happy I can hold the solar panel near
>>> >>> the point of peak efficiency but I am concerned about charge
>>> >>> termination due to the variable power available from solar panels.
>>>
>>> >>> Normally for NiCd I would use negative delta V for termination with a
>>> >>> back up timer. For NiMH I would use a thermistor for delta T
>>> >>> termination. However I can see potential problems with solar as the
>>> >>> power source.
>>>
>>> >>> In principle I could lay out a 60W panel in Arizona and charge the
>>> >>> batteries without problems - until someone parks a truck and shades
>>> >>> the panel dropping the charge current.
>>>
>>> >>> So what is the best way to terminate charge on nickel based batteries
>>> >>> with a variable power source?
>>>
>>> >>http://www.edn.com/file/25378-Solar_panel_powers_two_stage_lead_acid_...
>>>
>>> >---
>>> >OP: ... "nickel based batteries"...
>>>
>>> >BS: ... "lead acid battery charger"...
>>>
>>> >http://csmanagement.files.wordpress.com/2009/08/apple-and-orange.jpg
>>>
>>> Yep, diiferent. Lead acid and lithium are fairly easy to terminate the
>>> charge on as they use constant voltage charging.
>>
>>Nickel-based batteries are fairly easy to keep track off if you can
>>put a temperature sensor on the battery, and a reference temperature
>>sensor fairly close by.
>>
>>Once nickel cadmium bateries are fully charged, any further changing
>>liberates hydrogen gas at the cathode, which diffuses to the anode and
>>recombines with oxygen (from the metal oxide produced by the same
>>current) to produce water and heat - quite a lot more heat than is
>>generated by the same current when it is charging a less than fully
>>charged battery.
>>
>>"Interchangable" thermistors are quite stable enough to let you
>>reliably detect the consequent extra heating of the battery.
>>
>>http://en.wikipedia.org/wiki/Nickel-metal_hydride_battery
>
>---
>So it looks like, without expressly acknowledging your earlier
>boo-boo, you've admitted that your reference was bogus since a PV
>lead-acid charger won't work for NiMH.
>
>Unfortunately, and to your detriment, you still haven't addressed the
>OP's query, which was, basically, "What do I do if the sun goes behind
>a cloud while the battery is charging?"
>
>Instead, you parrot an expensive "Interchangeable thermistor" scheme
>to guard against overcharging, which the OP has already laid out, but
>which has nothing to do with PV shading during charging.
>
>The way I'd do it would be to completely disconnect the battery from
>the charging circuitry when the array was shadowed, and then reconnect
>it when the sun came out again.
>
>Got a better idea?


I remember reading a paper, which I can't find, years ago. The rough
idea was you could use short discharge pulses between charge pulses
and the voltage depression during the discharge pulse was related to
the state of charge.

Whether the technique actually works in practice is another matter,
but if it works then it wouldn't depend on the charge current being
constant.
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