From: Mike Vandeman on 21 Jun 2010 10:53 Hi, I'm reading a great paper published in PNAS: "The evolution of multicomponent systems at high pressures: VI. The thermodynamic stability of the hydrogencarbon system: The genesis of hydrocarbons and the origin of petroleum" http://www.pnas.org/content/99/17/10976.full.pdf+html The paper discusses thermodymanic stabity theory and presents model experimental results in which hydrocarbons are generated abiotically. The experiment involves cooking lab grade CaCO3 and FeO with triple- distilled H2O to exclude biota. The temperature and pressure used are found within the mantle of the Earth. Calcium carbonate is a barely representative mineral of the earth's minerals. FeO is a rare intermediate oxidation state of ion, more reduced than fully oxidized iron found in the crust and more oxidized than the molten iron core of the earth. Those few of you who have mastered high school chemistry will understand the chemistry. In the reactions studied by the authors, calcium carbonate provides a source of carbon in an oxidized state, FeO is a catalyst and reducing agent and H2O provides a source for hydrogen. Cook and squeeze under mantle conditions and you end up with an equilbrium mixture of complex hydrocarbons. The authors presentation of theory gives a graph for normal alkanes, alkenes, cycloalkanes and polyaromatics up to carbon number 20. All this seems compelling from the point of view of our knowledge of the solar system. We can see compex mixtures of hydrocarbons laying about on moons such as Titan. We know of the carbonaceous chondrites which contain what I would call asphalts. You can read about carbonaceous chondrites here: http://en.wikipedia.org/wiki/Carbonaceous_chondrites My reading of the wikipedia article is that the author leans towards a biological origin for the asteriod's materials. Let's dismiss that idea for a moment and ask ourselves, 'how did polyaromatic hydrocarbons like asphalt get hurtled into outer space?' If they were created in an abiotic process deep within the mantle of a planet, then we are talking about exploding planets much like Superman's planet Krypton exploded! However, the current dominant theory for the origin of our Moon is that our earth was explodied in a massive collision with a Mars size impactor. The debris reassembled into what is now the earth-moon system. This abiotic oil theory along with the currect genesis theory of the earth-moon systen suggests that there should be valuable concentrations of petroleum on the moon. My question to this congegrations is has any such evidence been observed and has any one bothered to look? Maybe oil seeps on the moon's surface might be visible by telescope? Objects as small as lunar rovers have been seen using powerful telescopes on earth,
From: dlzc on 21 Jun 2010 12:47 Dear Mike Vandeman: On Jun 21, 7:53 am, Mike Vandeman <MikeVande...(a)hushmail.com> wrote: .... > My question to this congegrations is has any such > evidence been observed and has any one bothered > to look? http://adsabs.harvard.edu/full/1970GeCAS...1.1879M http://www.lpi.usra.edu/meetings/LEA/whitepapers/AllenApolloOrganics.pdf "The organic compounds measured in Apollo samples are generally consistent with known sources of contamination." .... no oil in the few sites we sampled. David A. Smith
From: Cwatters on 21 Jun 2010 16:19 "Mike Vandeman" <MikeVandeman(a)hushmail.com> wrote in message news:f16e7ffd-bd9a-4065-8ebe-e25666bcfe1a(a)z13g2000prh.googlegroups.com... Hi, > >I'm reading a great paper published in PNAS: > >"The evolution of multicomponent systems at high pressures: VI. The >thermodynamic stability of the hydrogen�carbon system: The genesis of >hydrocarbons and the origin of petroleum" http://en.wikipedia.org/wiki/Abiogenic_petroleum_origin
From: Uncle Al on 21 Jun 2010 20:37 Mike Vandeman wrote: > > Hi, > > I'm reading a great paper published in PNAS: > > "The evolution of multicomponent systems at high pressures: VI. The > thermodynamic stability of the hydrogen�carbon system: The genesis of > hydrocarbons and the origin of petroleum" > > http://www.pnas.org/content/99/17/10976.full.pdf+html > > The paper discusses thermodymanic stabity theory and presents model > experimental results in which hydrocarbons are generated abiotically. 1) Petroleum compounds that are chiral are homochiral. 2) Petroleum carbon compounds have an extraordinary preference for even-numbered carbon compounds - acetate homologation. 3) Petroluem terpenoids and polyterpenoids. > The experiment involves cooking lab grade CaCO3 and FeO with triple- > distilled H2O to exclude biota. The temperature and pressure used are > found within the mantle of the Earth. Calcium carbonate is a barely > representative mineral of the earth's minerals. [snip] Yadda yadda. Won't reproduce the stereochemistry, even carbon number preference, and terpenoid (poly)cyclics that are flooding the Gulf at 70,000 bbl/day. Methane can be abiotic no problem. Petroleum and coal are degraded organisms. > My question to this congegrations is has any such evidence been > observed and has any one bothered to look? Maybe oil seeps on the > moon's surface might be visible by telescope? Objects as small as > lunar rovers have been seen using powerful telescopes on earth, Don't be an idiot. -- Uncle Al http://www.mazepath.com/uncleal/ (Toxic URL! Unsafe for children and most mammals) http://www.mazepath.com/uncleal/qz4.htm
From: spudnik on 23 Jun 2010 22:12 there is one theory, that Moon is a dead planet; that is, if one does not assume that all craters are via bolides, that the maria are basaltic seafloors, and the highlands being the finally acreted "Panluna." therefore, if residual water is to be found, mayhap also residual hydrocarbons. > The vacuum of the lunar surface makes anything of a conventional > liquid or fluid impossible. thus&so: are not there already several kinds of "surrogate factoring" in numbertheory ... is that a demonstration of the meaning Life, Universe and 42? yeah; the second Meander number! thus&so: that's about what Roemer did (no umlaut for the o, hereat). note that Vedic astrology included the precession of the equinoxes, whereas Western or Symbolic or Solar atrology doesn't; it is based upon Ptolemy's hoax, which had no epicylce for that well-known phenomenon. so, when a typical western astrologer does your sign, it is no-better than the twelve daily fortune-cookies in the newspaper -- Sydney Omarr is dead; long-live Sydney Omarr (TM) !! > > a + b + c + d = x^2 > > a^2+b^2+c^2+d^2 = y^2 > > a^3+b^3+c^3+d^3 = z^3 > If (a, b, c, d) is a solution then so is > (akk, bkk, ckk, dkk) > for any square kk. > Solutions for a,b,c,d < 1300 with > no such common square factor include > (0, 0, 0, 1) > (10, 13, 14, 44) > (54, 109, 202, 260) > (102, 130, 234, 318) thus&so: surely it could not be so hard, to find some of the rather definitive un-null results of Michelson, Morely et al; is it?... well, even as Albert the Witnit wobbled on the idea of aether, it is really a matter of interpretation. so, why cannot the electromagnetic properties of atoms in "space" be an aether; to wit, permitivity & permeability? should your "theory" can be taken at all seriously, you'd have to be able to explain such; would you not? oh, and there never was a twin paradox; it is just a "term of art" and pop-science. I mean, shouldn't the few properties of energy, of light, be of the ultimate importance for matter, per the experiments of Young, Fresnel et al, in utterly burying Newton's "theory" of corpuscles -- til it was rescued by the word, "photon; hereinat to be interpreted to mean a massless rock o'light?... and, thanks for that Nobel!" > Using Larmors transform, there is no twins paradox. --BP loves Waxman-Obama cap&trade (at least circa Kyoto, or Waxman's '91 cap&trade on NOX and SO2) -- how about a tiny tax, instead of the Last Bailout of Wall Street and the "City of London?" http://larouchepub.com/pr_lar/2010/lar_pac/100621pne_nordyke.html --le theoreme prochaine du Fermatttt! http://wlym.com
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