From: "Juan R." González-Álvarez on

TRAJECTORY BRANCHING IN LIOUVILLE SPACE AS THE SOURCE OF IRREVERSIBILITY

An introduction to irreversibility was given in the first part: The quest
for the ultimate theory of time, an introduction to irreversibility. In
this event, the author want to communicate the recent advances done in our
comprehension of irreversibility. This information is derived from a
research program in progress and must be taken with caution. However, the
research results obtained at the Center seem highly reasonable.

It is realized by an increasing number of physicists and chemists that the
solution of the problem of the "arrow of time" requires an extension of
classical and quantum mechanics. The XXIth Solvay Conference on Physics
has been devoted to Dynamical Systems and Irreversibility. There has been
no unanimity in choosing the way in which the extension of classical or
quantum mechanics has to be performed to include the dynamical description
of irreversible processes.

A selection of main fine-grained approaches is given in a recent
monograph: Resonances, instability, and irreversibility [1]. This includes
the work of the following authors —ordered by appearance on the content
index—: T. Petrosky & I. Prigogine; E. C. G. Sudarshan, Charles B. Chiu &
G. Bhamathi; Erkki J. Brändas; E. Eisenberg & L. P. Horwitz; I. Antoniou &
Z. Suchanecki; V. V. Kocharovsky, Vl. V. Kocharovsky, & S. Tasaki; Pierre
Gaspard; and C. A. Chazidimitriou-Dreismann.

In their work Unstable systems in generalized quantum theory, Sudarshan et
al. present us a generalization of quantum mechanics, beyond the standard
Dirac formulation, aimed to study the decay of unstable particles,
radioactive nuclei, and excited atoms, beyond phenomenological treatments
as the Breit & Wigner model.

Eisenberg & Horwitz review the recently developed quantum theory using the
ideas and results of Lax & Phillips. Their new framework for the
description of quantum unstable systems is based in a direct integral
Hilbert space. Two characteristic features are the generalization of the
dimensional time t = x^0 to the evolution parameter \tau —not to be
confounded with proper time!— and of the generator of time translations H
--> K, where H is the Hamiltonian. This generalized structure strongly
resembles that on the theory of Stuëckelberg, Horwitz, & Piron. An
analysis of the classical mechanics and electrodynamics of Stuëckelberg,
Horwitz, & Piron was given in a previous report CSR:20093v1 —you may find
additional information, in a post-publication note by Horwitz, in the
matching event—. An analysis of the quantum versions is now being
prepared; at the time of writing this, the draft is completed above the
80%.

The general problem of irreversibility is discussed in the papers by T.
Petrosky & I. Prigogine, and by I. Antoniou & Z. Suchanecki. They belong
to the Brussels-Austin School. An analysis of their last work is given by
Robert C. Bishop [2]. Internal analysis, by another member of the School,
is found in the section Toward a Grand Theory of Irreversibility? in a
last book by Radu Balescu [3]. The new work presented here solves many of
the objections and corrects some common misunderstandings: for instance,
many authors have misinterpreted the Brussels-Austin statements about the
collapse of trajectories.

Here and thereafter, the discussion is highly technical and focused to
experts in this highly-sophisticated subject. Research reports and
Perspectives for the general public will be prepared later.


LIOUVILLE SPACE BIFURCATION POINTS

The existence of bifurcation points —for which σ_E[t_b] · σ_S[t_b] + +
g[t_b] = σ_E[t_b] · σ_S[t_b] is fulfilled— is inferred from the
topological properties of the fundamental interactions for a N-body
system: L'_ES[t_b] = 0. This is studied in the topological structural
clusters program and may be understood as a generalization to condensed
phase systems of the Stosszahlansatz of the kinetic theory of gases.
However, no approximation is being done in the TSC formalism.

Branching in finite volumes is an emergent property, because no
bifurcation point exists in the Liouville space for one and two-body
particle systems. For those simple systems, one recovers the cluster
decomposition principle of quantum field theory as a special case of
branching valid in the limit of infinite volumes [4]. Its emergency
explains why particle physics could not solve the problem of
irreversibility.

Branching introduces irreversibility because trajectories are broken. This
confirms a main result obtained by the Brussels-Austin School, except that
the fundamental source for "the collapse of trajectories" are not Poincaré
resonances, but bifurcation points in Liouville space.

Irreversibility may be intuitively understood as follow —see the figure
below—. Before and after a bifurcation point, the propagator is
time-reversible and deterministic; the usual trajectory theory applies and
the equations are just the Liouville equations 1, 1', and 2. However, at
bifurcation points the evolution is not invertible. For instance, if at t
= t_b the factorization is σ_E[t_b] σ_S[t_b] = {6·2 --> 12}, its inversion
gives the collection of all the possible factorizations {12 --> 6·2}, {12
--> 3·4}, {12 --> 12·1}, {12 --> 2·6}, {12 --> (1/2)·24},..., with the
associated probabilities, instead of just {12 --> 6·2} with probability
one —indeed, this is the deep reason which one sums or integrates over all
the possible final states compatible with a given initial state in the
usual master equations—. As a consequence of the no-invertibility at t =
tb, the global evolution is neither time-reversible nor deterministic.

The whole equation of motion 3 can be obtained from analyzing the overall
evolution, including the bifurcation points at t = t_b and t = t'_b. As a
help to infer the exact form of the whole propagator, I have used a slight
generalization of Balescu diagrams [3]. The first two terms are the
free-motion propagator and the open Y-vertex giving a Vlasov evolution.
Both terms are reversible and correspond to the mechanical term M in the
canonical equation of motion —see the postulate (iii) in canonical theory
as a unified Cosmovision—. The terms inside the curly brackets are
irreversible and correspond to those terms of the canonical equation of
motion denoted with curly brackets too. A fundamental difference with
Keizer's original canonical equation is that the Markovian approximation
is no longer used, which means that now \Omega = \Omega[t].

{{{{ FIGURE }}}}


A FOUNDATION FOR THE BRUSSELS-AUSTIN THEORY

Several years ago, in one of our conversations, I asked Prigogine a bunch
of questions. One of them was: "Are Poincaré resonances the basis for the
Second law?". His response (9 May 2003) was: "The questions that you ask
are very difficult" and added "I wish you much success". He passed away
nineteen days after. I only can imagine his reaction to those recent
research results if he was living today, but I believe that he would be
very pleased by them.

From the analysis of the overall evolution sketched in the above section,
one can obtain the equation for the average correlations in 2 as

g = L_V/(D − L_0) σ_E σ_S + O(L_V^2)

The Markovian regime is obtained setting D = 0. Multiplying and dividing
by i and switching to the Brussels-Austin School (BAS) notation, L^BAS ==
iL, yields

g = L_V^BAS/(i0 − L_0^BAS) σ_E σ_S + O((L_V^BAS)^2)

This is essentially equivalent to the BAS result for the class of LPSs.
They obtain it from a different way [1]. They start from the spectral
decomposition for LPSs, which will include singular denominators
associated to a continuous spectrum L_0^BAS --> 0. Prigogine and coworkers
regularize them adding a small \pmi\epsilon with \epsilon a positive
infinitesimal \epsilon --> 0+. The new denominator (L_0^BAS \pmi\epsilon)
can be understood as arising from a complex eigenvalue extension of the
usual Liouvillian.

There is two possible analytic continuations: the positive and the
negative branches. One of them is compatible with the Second law and the
other is not. Prigogine and coworkers then choose the branch compatible
with observations [1]. Note that this is not a derivation of the Second
law from microscopic details but that the law is being used to eliminate
the ambiguity associated to the Poincaré resonances of the BAS formalism.
This is easy to understand; resonances are essentially an energetic
concept and the Second law defines irreversibility in terms of entropy,
not of energy. Alternatively, we can obtain the correct branch +iε
directly from the condition D > 0 for 3, without any appeal to the Second
law.

Irreversibility for the finite systems around us is thus rooted in the
existence of bifurcation points. In the limit of an infinite system, an
alternative description in terms of a complex extended Liouvillian with
Im(Z^BAS) =< 0 can be obtained. However, no real system is infinite and
the new theory for finite systems is preferred.

Other BAS main results can be re-derived here. For instance, the new
theory gives generalized Lippmann & Schwinger equations. For a LPS one
sets D = 0 and L_0^BAS = 0, and the generalized equations reduce to σ_E ·
σ_S + g --> σ_E · σ_S + L_V^BAS/(i0 − L_V^BAS) σ_E σ_S

This implies that the Hilbert space norm vanishes <<σ_E · σ_S + g | σ_E ·
σ_S + g>> --> 0 in the limit of infinite system. The BAS takes this result
as the confirmation that distributions of this kind do not belong to the
Hilbert space [1]. They propose a Rigged Hilbert space as a more adequate
algebraic structure. However, the Hilbert space norm is nonzero for the
more realistic finite systems studied in the new theory.

Another interesting result is the explanation of the factorization σ = σ_1
· σ_2 ··· σ_N for a LPS. This result follows directly from the TSC theory,
without any appeal to special cosmological boundaries as in the BAS
approach [1]. Furthermore, the cosmological models derived from canonical
science are much more general and, as pointed in previous events, explain
observations that none other approach does.

There exist other advantages over the BAS formalism but are not directly
associated to irreversibility and will be not discussed here.

In the third part, Toward a grand theory of irreversibility, I will sketch
how this new theory reproduces the known pragmatic and
semi-phenomenological quantum approaches developed in the last decades by
at least six communities: NMR chemists, quantum optics, condensed matter
physicists, mathematical physicists, astrophysicists, and condensed phase
chemical physicists [5]. And will sketch the advantages and
generalizations over the current approaches.


REFERENCES AND NOTES

[1] Resonances, instability, and irreversibility 1997: Adv. Chem. Phys.
99. Several authors.

[2] Brussels-Austin Nonequilibrium Statistical Mechanics in the Later
Years: Large Poincaré Systems and Rigged Hilbert Space 2003:
arXiv:physics/0304020v3. Bishop, Robert C.

[3] Statistical Dynamics, Matter out of Equilibrium 1997: Imperial College
Press, London. Balescu, Radu.

[4] The Cluster Decomposition Principle In The Quantum Theory of Fields,
Volume 1 Foundations 1996: Cambridge University Press, Cambridge;
Reprinted with corrections. Weinberg, Steven.

[5] Phase space approach to theories of quantum dissipation 1997: J. Chem.
Phys. 107(13), 5236—5253. Kohen, D.; Marston, C. C.; Tannor, D. J.


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From: "Juan R." González-Álvarez on
Surfer wrote on Tue, 01 Jun 2010 11:22:57 +0930:

> On Mon, 31 May 2010 14:56:55 +0000 (UTC), "Juan R." González-Álvarez
> <nowhere(a)canonicalscience.com> wrote:
>
>
>>TRAJECTORY BRANCHING IN LIOUVILLE SPACE AS THE SOURCE OF IRREVERSIBILITY
>>
> Original text here:
> http://www.canonicalscience.org/publications/canonicalsciencetoday/20100531.html

Yes, the above is the permanent link.

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